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High frequency (1-2 kHz) Raman spectroscopy was employed to monitor the formation and phase transition of in situ gelling biopolymer hydrogels, which are formed in response to changes in pH. A liquid precursor was synthesized, containing monomers such as N-isopropylacrylamide (NIPAM), N-vinyl pyrrolidone (NVP) and glutaraldehyde (GA), which upon the addition of water form a hydrogel. Raman spectroscopy was used to examine this liquid precursor, as well as precursor-polymer gel mixtures and polymer gels containing varying fractions of NVP, before and after pH cycling. The Raman vibrational modes of interest were used to characterize the chemical composition of precursor, precursor-polymer gel mixtures and polymer gels. In addition, the characteristic vibrational modes of the carbonyl and carboxylate groups present in GA were used to monitor changes in the backbone structure of the polymer gels as a function of pH. The formation of a physically-crosslinked polymer gel was accompanied by shifts in the intensity of the NIPAM-stretching mode and appearance of a carbonyl vibration band. Upon addition of a crosslinking agent, the gel transition was associated with a more dramatic shift in the NIPAM-stretching mode, and disappearance of the carbonyl and carboxylate vibrations. The changes in the vibrational modes of these two groups as a function of the degree of crosslinking suggest a strong contribution of the carboxylate group to the physical crosslinking in the polymer gel.The invention relates to a contact arrangement for a display apparatus and to a display apparatus having such a contact arrangement.
Display apparatuses are known which have eea19f52d2

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Synei Backup Manager is a powerful backup software utility that helps you create backups for your programs, system, and application files. It can even backup various content items from your removable media. You can use the program to backup and recover data from a variety of external and internal media. The program has an intuitive graphical user interface that makes backup creation quick and easy. The program has an optional encryption capability.
Features:

Backup and restore your system or application files, data and settings.
Backup your most used data, application, program and network files.
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Backup files, folders or drives to any of your portable media (hard disk, USB, etc.)
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